A New Polydentate Ligand and it’s Cu (II) Complex – Synthesis and Characterization

Desta, W/Tsadik (2007) A New Polydentate Ligand and it’s Cu (II) Complex – Synthesis and Characterization. Masters thesis, Addis Ababa University.

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Abstract

Dinuclear Copper (II) complex of a bis-chelating 4,6 – Bis{[((imidazo-5-yl) methyl) hydrazo] ethyl }-benzene-1,3-diol was synthesized and characterized by using conductivity, magnetic susceptibility measurement, IR and UV-VIS spectra. BIMHEBD was synthesized by the condensation of 2, 4-dihydroxy-5-acetylacetophenone dihydrazone (DAAD) with 4(5) – imidazo carboxo aldehyde. The ligand behaves as dibasic bis-tridentate chelating system through ONN-ONN donor sequence. Subnormal magnetic moment of the complex indicates the possibility of antiferomagnetic interaction through a possible superexchange mechanism.

Item Type: Thesis (Masters)
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Africana
Depositing User: Selom Ghislain
Date Deposited: 27 Jun 2018 08:16
Last Modified: 27 Jun 2018 08:16
URI: http://thesisbank.jhia.ac.ke/id/eprint/5991

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